Identify the numbers to be subtract. For example, suppose you need to subtract pi from 2pi/3. In angle measurements, pi radians corresponds to 180 degrees.
Convert pi to a fraction. To do this, multiply it by a fraction that equals 1; this fraction will have a numerator (top number) and denominator (bottom number) that is the same as the denominator of the fraction it is being subtracted from. In the example, you would multiply pi by 3/3 to get 3pi/3.
Subtract the fractions as normal. The final answer in the example would be 2pi/3 - 3pi/3, which equals -pi/3.