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How to Determine the pKa of the Unknown Acid Without Using a pH Meter

The pKa value of an acid is the negative base 10 log of its dissociation equilibrium constant. This value is critical in many chemical reactions and procedures such as acid-base titration. The Ka value of an acid represents the rate at which the dissociation creates hydrogen ions. This directly influences the pH of an acid solution. When a pH meter is not available, you can determine the pKa of an acid using a pH indicator, such as litmus paper, designed for the 2 to 7 pH range.

Things You'll Need

  • Litmus paper
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Instructions

    • 1

      Dip a piece of litmus paper into the acid solution. Submerge it for only a few seconds, then allow it to dry on a nonreactive surface.

    • 2

      Compare the color of the litmus paper against the standards provided with its kit. To find the pH, match the developed color to the most similar color in the comparative charts.

    • 3

      Raise the negative of the pH to the base 10. For example, if the pH is 3.2, raising it to the base 10 will give 10^-3.2. This yields the hydrogen ion concentration in the acid solution.

    • 4

      Square the hydrogen ion concentration and divide it by the molarity of the acid. This operation yields the rate constant, known as the Ka, for the solution.

    • 5

      Take the negative logarithm of the Ka value. This yields the pKa of the unknown acid.

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