Look at the device's power plug. If it uses a standard household outlet, the voltage is 120 volts. If it plugs into a large, oddly shaped receptacle, then it's likely to use 240 volts.
Reference the device's wattage, which should be printed in the device's specifications or manual.
Divide the wattage by the voltage to calculate the number of amps. As an example, an 1,100-watt microwave would use 9.17 amps, because 1,100 divided by 120 equals 9.17.