Here's a representation showing the basic consonants (the order might vary slightly depending on the system used):
ক (kɔ) - ka
খ (khɔ) - kha
গ (ɡɔ) - ga
ঘ (ɡɦɔ) - gha
ঙ (ŋɔ) - ŋa
চ (tʃɔ) - cha
ছ (tʃʰɔ) - chha
জ (dʒɔ) - ja
ঝ (dʒʰɔ) - jha
ঞ (ɲɔ) - ña
ট (ʈɔ) - ṭa
ঠ (ʈʰɔ) - ṭha
ড (ɖɔ) - ḍa
ঢ (ɖʰɔ) - ḍha
ণ (ɳɔ) - ṇa
ত (tɔ) - ta
থ (thɔ) - tha
দ (dɔ) - da
ধ (dhɔ) - dha
ন (nɔ) - na
প (pɔ) - pa
ফ (phɔ) - pha
ব (bɔ) - ba
ভ (bhɔ) - bha
ম (mɔ) - ma
য (dʒɔ) - ya (often the same as জ but with a different vowel sound)
র (rɔ) - ra
ল (lɔ) - la
শ (ʃɔ) - śa
ষ (ʃɔ) - ṣa
স (sɔ) - sa
হ (hɔ) - ha
Vowels:
অ (ɔ) - a (short a)
আ (a) - ā (long a)
ই (i) - i (short i)
ঈ (iː) - ī (long i)
উ (u) - u (short u)
ঊ (uː) - ū (long u)
ঋ (r̥) - ṛ (a less common vowel)
এ (e) - e
ঐ (oi) - oi
ও (o) - o
ঔ (ou) - au
This isn't a complete representation; there are additional conjunct consonants (where two or more consonants are combined) and other nuances. Trying to force a direct A-Z comparison loses the essence of the Bengali script. It's better understood as a unique system with its own logic.
To see the letters correctly, you'll need a font that supports Bengali script.