Therefore, you'd use "shiniest" in most cases. However, "most shiny" might be preferred in certain contexts where it sounds more natural or emphasizes a particular aspect of shininess (though this is subjective).
Examples:
* Shiniest: "Of all the apples, this one is the shiniest."
* Most shiny: "This apple has the most shiny surface." (Slightly awkward, "shiniest" is better here)
In short, while both are grammatically possible, "shiniest" is the generally preferred and more concise option.