How to Anodize Zinc

Anodizing is the process whereby a layer of metal oxides is created on the surface of the metal, in order to strengthen the metal, increase corrosion and wear resistance and provide better adhesion for paint primers and glue.



While zinc is rarely anodized, the International Lead Zinc Research Organization developed a protocol for anodizing zinc. Before anodizing zinc, anneal (soften using heat treatment), making surface treatment procedures more efficient. Then treat, processing in electrolytes (ie, 0.01 M phosphoric acid), while passing voltage currents through electrolyte liquid at 40 V. This anodization leads to the production of olive green surface zinc oxides, about 80 micrometers thick, along with water.

Things You'll Need

  • Pure zinc foils (purity 99.9%)
  • Acetone
  • Ultrasonic bath
  • Ethanol
  • Nitrogen gas
  • Beaker or glass cell
  • Stir bars
  • Stir plate
  • Two-electrode system with platinum as the working electrode -- connected to a power source interfaced to a computer
  • Argon gas
  • Phosphoric acid
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Instructions

    • 1

      Anneal zinc foils at 300 degrees Celsius for 5 hours in the presence of argon gas.

    • 2

      Clean the zinc foils using acetone. Pour acetone into an ultrasonic bath and add the zinc foils. Turn the ultrasonicator on to expose the zinc and acetone to continuous vibrations. Pour out the acetone, wash the zinc with ethanol and dry it with nitrogen gas.

    • 3

      Set up for anodizing. Pour phosphoric acid into a beaker, or glass cell, if available. Place the two-electrode setup into the phosphoric acid. Connect the zinc sheets to one of the electrode terminals. Zinc is the "working" electrode, which is connected to the power source and is responsible for delivering voltage into the phosphoric acid. Connect the platinum, the counter electrode, to the other electrode terminal. Platinum will work to balance or remove the charge contributed by zinc. Add a stir bar to the beaker or glass cell and place it on a stir plate. Stir the setup at a constant rate over the duration of the anodizing procedure.

    • 4

      To verify and quantify anodization, use a scanning electron microscope to quantify the sizes of the pores formed on the surface as a result of step 3.

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