Four Things That Affect Rate of Diffusion

Diffusion is the process by which atoms of one material are transferred into another material through random atomic motion. In diffusion, a material moves from areas of high concentration of that material into areas of low concentration of that material. A common example of diffusion is when a gas spreads out to fill a room or to move through a wall. The rate at which diffusion occurs depends on a variety of factors.
  1. Temperature

    • Of all the factors that influence diffusion rate, temperature is the most important. Temperature has the greatest effect on diffusion rates and is the easiest of the factors to change. Increasing the temperature increases the diffusion rate by adding energy to each particle. This is because particles with more energy can move through the host material more easily. Similarly, lowering the temperature will lower the diffusion rate by lowering the energy of each particle.

    Concentration Difference

    • The rate of diffusion depends on the difference between concentrations across the host material, with higher concentration differences resulting in higher diffusion rates. For example, diffusion through a thin wall will occur significantly faster if there is a high concentration of the gas on one side and none of the gas on the other side of the wall, than if there was an almost equal amount of gas on both sides.

    Diffusion Distance

    • The rate of diffusion is inversely related to the distance through which the material is diffusing. That is, smaller distances result in faster diffusion rates and larger distances result in slower diffusion rates. This makes sense, since a gas diffuses through a thin wall much faster than it would diffuse through a thick wall.

    Diffusing and Host Materials

    • Diffusion rate also depends on both the material that is diffusing and the material it is diffusing through. At a certain temperature, all particles have the same average energy. This means that lighter atoms, such as hydrogen, carbon, oxygen and nitrogen travel faster and are more mobile than larger atoms such as copper or iron. Materials made of these lighter atoms diffuse faster than heavier materials.

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