Create a set in the form of (number of trials, relative frequency) that can be easily plotted. When performing trials it may be convenient to record results in spreadsheet software for easy plotting.
Run a large number of trials. The larger the number, the more accurate your result will be. If your data is of a limited number of trials or time period, cut it into as many sections as possible.
Plot the relative frequency against the number of trails. This is best performed with statistical or mathematical software such as R, SPSS or SAS.
Observe the convergence of the graph. The number the graph converges to as the number of trials increases is the probability of the event as defined by the long-term relative frequency.