Different Gas Laws

The gas laws are a collection of observations that explain the behavior of gases. The famous gas laws were described hundreds of years ago and then incorporated into the modern fundamental law of ideal gasses. Numerous other minor laws by chemists, both famous and not so famous, round out our understanding of gas--the most ephemeral state of matter.
  1. The Famous Gas Laws

    • Boyle, Charles and Gay-Lussac are immortal in chemical lore because they discovered experimentally--in three consecutive centuries--the laws of gases. In 1622, Boyle discovered that if the temperature remains constant, the product of the pressure and the volume remains constant, or In modern terms: for constant temperature, pressure and volume are inversely proportional--if one goes up, the other goes down. In 1787, Charles reveled that when the pressure is constant, the volume and temperature are proportional--if one goes up, so does the other. In 1809, Gay-Lussac showed that whenever the volume is constant, the pressure on the walls of a container of gas is proportional to the temperature.

    The Fundamental Gas Law

    • The fundamental gas law (also known as the ideal gas law) incorporates Boyle's law, Charles's law and Gay-Lussac's law into one equation: PV = nRT. In this equation, P is pressure, V is volume, n is the number of gas molecules, R is a constant that depends on what units are being used and T is the temperature (in degrees Kelvin). Put your fingertip over the T to get Boyle's law: "If temperature is constant, the product of the pressure and the volume is a constant." similarly, you can get Charles's law by covering the P, and Gay-Lussac's law by covering the V. The ideal gas law gives the relationship between pressure, volume and temperature for n moles of a gas. If the gas is unconfined, the pressure goes to zero and the volume expands infinitely.

    Other Gas Laws

    • Dalton's Law states the the total pressure of a mixture of gases is the sum of the pressures of the individual gases. Avogadro's law says that the volume of a gas is proportional to the number of moles of the gas. Henry's law reveals that, at a constant temperature, the amount of gas that is dissolved in a liquid is proportional to the partial pressure of the gas in the container. Graham's law shows that the rate that a gas diffuses in inversely proportional to the density of the gas.

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