Here's a breakdown:
* 500s: Natural Sciences and Mathematics
* 540s: Chemistry
Within the 540s, you'll find specific categories like:
* 540: General Chemistry
* 541: Physical Chemistry
* 542: Analytical Chemistry
* 543: Inorganic Chemistry
* 544: Organic Chemistry
* 545: Biochemistry
* 546: Nuclear Chemistry
* 547: Macromolecular Chemistry
* 548: Crystallography
So, if you're looking for a book on organic chemistry, you would look for it in the 547s.